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Consider the interaction between two sp n hybridized orbitals of unequal energy interacting in a s fashion The interaction diagram is illustrated in Figure 41a Notice that the hybridization of the sp n group orbitals in the s orbital appears to be turned inside out This is in recognition that much cancellation will occur due to the node in the middle The lowest energy con guration has two electrons with energy e L , as shown Not much can be said about the absolute magnitudes of he L and he U , but we are concerned here with trends The rst series (C, N, O, F) involves atoms which are very approximately the same size but di ering greatly in electronegativity The interaction matrix element, hCX , will be essentially constant across the series X C, O, N, F.

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and are the Coulomb and exchange integrals, respectively. Thus,

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However, relatively large changes will occur in the di erence in orbital energies, the quantity e C e X increasing in the series The consequent energies of the resulting s and s orbitals are shown in Figure 42 In each of the two interaction diagrams shown and the two implied in between, the energy of the sp n orbital of the C atom is drawn at the same level The energies of both the bonding s orbital and the antibonding s orbital decrease, being the lowest for the C F bond The greatest polarization also occurs in the case of the C F bond In particular, the low-lying s orbital is highly polarized toward the C end of the bond.

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Unlikc FCA, the channel distribution in DCA adapts over time. Instead of predicting and averaging, DCA takes advantage of multiuser channel and traffic diversity to adjust the channel allocation over time. Although DCA requires higher computation complexity and signaling overhead during operation, its ability to utilize real-time system information leads to higher spectrum efficiency, especially with low to moderate traffic loads [6] [7]. Basically, DCA can be divided into two categories: centralized allocation and decentralized/distributed allocation.

The second series, involving bonding of C to di erent halogens (F, Cl, Br, I) involves atoms which are very di erent in size and also di ering greatly in electronegativity The halogen ends of the bonds are constructed from 2p, 3p, 4p, and 5p orbitals, respectively The overlap, and therefore the interaction matrix element, hCX , will decrease very rapidly across the series, X F, Cl, Br, I Relatively large changes will also occur in the di erence in orbital energies, the quantity e C e X decreasing in the series The relative properties and reactivities of C X bonds are consistent with dominance of the interaction matrix element (ie, overlap dependence) in determining the resulting orbital.

to this question by producing an abstract model in 1982 that showed how a quantum system could be used to do computations In 1985, Deutsch realized one could conceive a general-purpose quantum computer; Deutsch published a seminal paper showing that any physical process, in principle, could be modeled perfectly by a quantum computer; hence a quantum computer would have capabilities far beyond those of any traditional classical computer Work has continued in earnest since then [671, 672, 673, 674] Refer to text for complete discussion Computing: ubiquitous computing Term coined by Mark Weiser in 1988; concept envisions computers embedded in walls, in tabletops, and in common objects In this environment, an individual could interact with hundreds of computers at a time, each invisibly embedded in the environment and wirelessly communicating with each other [675] In this environment, the technology recedes into the background.

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