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1335 Consider the gas-phase isomerization reaction: A+B (a) Assuming ideal gases, develop from Eq (1328) the chemical-reaction equilibrium equation for the system (b) The result of part (a) should suggest that there is one degree of freedom for the equilibrium state Upon verifying that the phase rule indicates two degrees of freedom, explain the discrepancy 1336 A low-pressure, gas-phase isomerization reaction, A-B, occurs at conditions such that vapor and liquid phases are present (a) Prove that the equilibrium state is univariant (b) Suppose T is specified Show how to calculate X A , y ~and P State carefully, and , justify, any assumptions 1337 Set up the equations required for solution of Ex 1314 by the method of equilibrium constants Verify that your equations yield the same equilibrium compositions as given in the example 1338 Reaction-equilibrium calculations may be useful for estimation of the compositions of hydrocarbon feedstocks A particular feedstock, available as a low-pressure gas at 500 K, is identified as "aromatic C8" It could in principle contain the CsHlo isomers: o-xylene (OX), m-xylene (MX), p-xylene (PX), and ethylbenzene (EB) Estimate how much of each species is present, assuming the gas mixture has come to equilibrium at 500 K and low pressure The following is a set of independent reactions (why ):
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rows This attribute sets the number of rows in the text area The value of the attribute should be a positive integer
boolean empty( )
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(a) Write reaction-equilibrium equations for each equation of the set State clearly any assumptions (b) Solve the set of equations to obtain algebraic expressions for the equilibrium vaporphase mole fractions of the four species in relation to the equilibrium constants, K I , K I I ,KIII (c) Use the data below to determine numerical values for the equilibrium constants at 500 K State clearly any assumptions (d) Determine numerical values for the mole fractions of the four species Species
Returns true if the stack is empty, and returns false if the stack contains elements Returns the element on the top of the stack, but does not remove it Returns the element on the top of the stack, removing it in the process Pushes element onto the stack element is also returned
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