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selenium oxide, and tellurium oxide as chalcogenide precursors149 154 The electrochemical growth processes have been widely studied The lms have been found to be stoichiometric by XPS and electrochemical stripping measurements The thin lms of CdS had the hexagonal wurtzite structure149 151 AFM studies of the CdS lms showed large clusters homogeneously distributed in the lms, with the size and density of these clusters not changing with an increasing number of deposition cycles149 EXAFS studies showed the presence of a tetragonal structure in the CdSe lms153 Cadmium sulphide selenides, CdSxSe1 x, and ternary cadmium and zinc sulphides and selenides, CdxZn1 xS, CdxZn1 xSe, have also been grown by ECALE155 157 The ratio of cation and anion was close to 1 : 1 as determined by XPS AFM revealed that the growth was both by two- and three-dimensional growth.

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156,157 The band gap was linear, following the composition of the lms CdTe lms have been grown epitaxially on Au154 The lms were produced by the alternate reductive underpotential deposition of Te and Cd The epitaxial growth was con rmed by STM154 Lead nitrate complexed with EDTA and lead perchlorate and sodium sulphide have been used for PbS ECALE-deposition158,159 The lms were cubic and highly (200) oriented, and AFM images showed the same cubic structure158,159 PbSe lms were also cubic, and the band gap of a lm after 50 deposition cycles was 8000 cm 1160 PbSe/PbTe superlattices, with 42-nm and 70-nm periods, have been grown by ECALE161 The (111) re ection in the XRD pattern showed a rst-order satellite peak and one second-order peak, indicating the formation of the superlattice.

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AFM images of the superlattice structure showed a small amount of three-dimensional growth161 Bismuth nitrate together with sodium sulphide and tellurium oxide have been used to grow bismuth chalcogenide lms162 166 The stoichiometric ratio 2 : 3 has been con rmed by XPS, EDX, and XRD162 166 The Bi2Te3 lms were rough and consisted of particles with a diameter of 30 100 nm, and electron probe microanalysis showed a worm-like network structure164 166 Antimony telluride lms have been grown from antimony(III) and tellurium(IV) oxides167 Antimony telluride lms were stoichimetric and consisted of nanoscale particles of the size 100 nm The lms had a good crystallinity167 Indium selenide lms were grown from indium sulphate and selenium oxide precursors168 The lms consisted of large particles, 70 to 200 nm in diameter The band gap was 173 eV.

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