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That might be a problem if you re trying to render a smoothly, reflecting mirror ball, but all I was going to use it for was to add some shiny spots on the leaves, so accuracy was not a goal..

IrDA communicator program (Continued).

FIGURE 32.2 Monomers: Small unsaturated (double-bonded) molecules that are building units for large polymer molecules. (a) Ethylene; (b) vinyl chloride; (c) urea; (d) benzene; (e) phenol; (f) formaldehyde.

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fluoride. The vinyl chloride monomer, as shown in Fig. 32.2b, is similar to ethylene except that one of the hydrogen atoms is replaced with a chlorine atom. The polymerization of this monomer results in polyvinyl chloride. These macromolecules resemble, more or less, smooth strings or chains, as can be seen from their structural arrangement. Some macromolecules resemble rough chains that is, chains with many short side arms branching from them. Polystyrene, which is a very important industrial polymer, is of this type. The styrene monomer is made from the benzene ring (C6H6) with one of the hydrogen atoms replaced with a CH CH2 molecule, as shown in Fig. 32.4a. Polymerization then occurs by breaking the double bond in the CH CH2 group with the help of a peroxide catalyst and joining two of them together, as shown in Fig. 32.4b. The polymers just described are thermoplastic; they melt or soften when they are heated. This is due to the fact that the individual macromolecules are stable and the linkages to other macromolecules are loose (since they are attracted to each

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FIGURE 32.3 Addition polymerization. (a) Three individual monomers of ethylene; (b) a portion of a polyethylene molecule formed when each double bond of the monomers is broken by a catalyst to form two single bonds and join the individual molecules together.

Downloaded from Digital Engineering Library @ McGraw-Hill (www.digitalengineeringlibrary.com) Copyright 2004 The McGraw-Hill Companies. All rights reserved. Any use is subject to the Terms of Use as given at the website.

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In computer graphics, there are two common techniques for mapping a scene onto a texture: spherical environment mapping and cube environment mapping. In this case, you ll map the scene surrounding you as mapped on a sphere centered at your location. In the other case, the scene will be mapped into each of the six sides of a cube centered at your location. For this implementation, I went with spherical mapping because it is a bit faster to compute, and the resulting quality is plenty for these needs.

FIGURE 32.4 (a) Styrene structure; (b) polystyrene structure. The polymerization takes place in the presence of a peroxide catalyst.

other by weak van der Waals forces). Some polymers are thermosetting; they do not soften when they are heated, but retain their set or shape until charred. This is due to the fact that the individual macromolecules unite with each other and form many cross-linkages. Bakelite (phenol formaldehyde) is such a polymer. Figure 32.5 shows how each formaldehyde monomer joins two phenol monomers together, under suitable heat and pressure, to form a macromolecule. This is a condensation type of polymerization because one water molecule is formed from the oxygen atom of each formaldehyde molecule and a hydrogen atom from each of the two phenol molecules.

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