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establishing the nature of the grains He proposed that, by using instruments on balloons at 100 000 ft, decisive studies might be made at 2200 The Polariscope Programme involving a balloon-borne instrument for ultraviolet measurements has been referenced by Gehrels (1972) Other early colour dependent observations were presented by Gehrels & Meltzer (1966) Although the paper of Coyne & ehrels (1967) is subtitled interstellar polarization , seven of the discussed stars are noted as displaying variable polarization, indicating that at least some elements of the measured values were intrinsically generated Striking differences from the then current mean interstellar p ( ) curve were found near Orion Wickramasinghe (1969) proposed mixtures of graphite silicate grains, the model giving rise to a broad maximum in the p ( ) curve at 5000 Further colour measurements were made by Coyne & Wickramasinghe (1969) with the general behaviour being discussed in terms of a composite interstellar grain model with a graphite core and dielectric mantle Early colour measurements by Serkowski (1968) demonstrated the correlation between regional variations in the wavelength dependence of interstellar extinction and polarization Again by using standard UBV lters, data assembled by Serkowski & Robertson (1969) showed that the ratio of p V /p B depends on galactic longitude In a review paper, Serkowski (1973) showed that there are well de ned regions in the sky where max is higher than average As noted earlier, values of max correlate well with R, the ratio of total to selective extinction In the same paper, the law, now referred as the Serkowski law, describing the general behaviour of the wavelength dependence of interstellar polarization was presented By taking the p ( ) values of individual stars and normalising them to their determined maximum value, p max , occurring at some wavelength, max , and by normalising the wavelength values, , to max , an overall plot of p /p max against max / produces a unique curve (Figure 103) described by an empirical formula of the form p ( ) max , (101) D exp K ln2 p ( max ) with K 115 being the same for all stars The algebraic representation above was originally proposed by Serkowski (1971),but with an erroneous value for K which the later paper (Serkowski, 1973) con rmed as being a misprint The method of tting data to Serkowski s law by a least-squares procedure is given by Coyne, Gehrels & Serkowski (1967) In this same paper, values of max and p max are listed for 202 stars, and the form of Serkowski s law is compared with models based on dielectric cylinders subject to the Davis Greenstein (see later) orientation mechanism The value of K used in Serkowski s law is a mean taken from measurements of many stars Codina-Landaberry & Magalh es (1976) have considered the role that it takes in relation to the individual value of each star, suggesting that it can act as an estimator of the discrepancy among particle sizes along the line of sight Differences in determined values of K are clearly shown in the observations of Clarke (1986) for the stars o Sco and Sco With the advent of 2D detectors, it has.

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