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the experiment the water concentrations are higher at the reactor outlet than at the inlet Only with decreasing per-pass conversions at higher total conversion levels can the overall water content be decreased In order to understand the maxima and the minimum of the instantaneous selectivity Sinst, it is useful to plot the predictions of the kinetic model as represented by the two rate Equations (1) and (2) In Fig 831, the Sinst expected from the kinetics is plotted depending on the fraction of water stripped from the liquid All these curves start at around 75 %, increase to near-unity, and then show a sharp drop at high inlet conversion levels Depending on the fraction of water stripped, the slope of the initial increase and onset of the final drop of Sinst differ.

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hence can be obtained by integrating the PDF of GSC , which can be obtained in closed form with the help of [36, Eq. (3.351.1), p. 357] as

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The difference in initial slope is attributed to the different number of catalytic sites involved in the two reactions If water is stripped from the liquid, coverage of the catalyst surface with water molecules decreases, and in consequence both reactions are running faster However, the increase of ether formation is proportional to the square of the progress of the esterification, because of the square in the adsorption term in the ether rate expression (3) Therefore, stripping of water increases the rates, but lowers the selectivity at low conversion levels If the conversion level increases, the reactant concentrations decrease As the esterification is of first order in acid, but the etherification of second order in alcohol, the latter suffers more from low reactant concentrations In consequence, the instantaneous selectivity increases with increasing conversion levels The sharp drop at high conversion levels is caused by the equilibrium limitation of the esterification.

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If the equilibrium is reached, no more ester is formed, whereas the etherification continues As the equilibrium depends on the water concentration, the drop of Sinst to zero occurs at higher conversion levels, if water has been stripped from the liquid..

for protein synthesis occurs by a two-step interorgan process: Glutamate is converted to omithine and then to citrulline in the intestinal mucosa. The kidney then utilizes citrulline to synthesize arginine.

Besides recording every column value change to an audit table, I like to record some generic audit data right in the row: Created column to record the date the row was inserted Modified column to timestamp the last update Version column to count the number of times the row has been updated AutoAudit adds these three columns to any table, and code-gens the trigger code to keep the modified and version columns up-to-date. This version is limited to tables with single-column primary keys. (That s not likely to change anytime soon, because modifying the audit table on the y to handle composite primary keys adds too much complexity and only a few have requested the feature.) It s written to be compatible with SQL Server 2005 and SQL Server 2008.

A molecule with n atoms can be described by a Cartesian system whose origin is at the center of mass and whose axes correspond to the inertia axes. An atom i with mass m, performing a motion is characterized by its equilibrium coordinates aio(a = x, 4 z and ;) its general coordinates a;. Displacement from the equilibrium position is described by A(T;= (T, m,o. The column vector xi, ..., z is noted X , the corresponding row vector is , the transposed vector noted XT. The kinetic energy T of the molecule can be expressed by

Organizer pane and choose the New Diagram option to de ne a new diagram, and then drag and drop tables from the lower-left corner Tables pane to add tables to the new diagram. Alternately, right-click the diagram and use the Show Tables dialog to include tables currently in the <All Tables> diagram. However, don t confuse the Show Tables dialog, which determines the data source view in which tables appear in a given diagram, with the Add/Remove Tables dialog, which determines which tables are in the data source view as a whole. FIGURE 71-2 The Edit Relationship dialog

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