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often have to be painstakingly entered manually into separate computer systems every time a person who is not a member of a speci c department needs ad hoc information related to the speci c department. In many cases employees simply do not get the information they need, or they get it too late. Sandoe et al. (2001) list the following major bene ts of systems integration (in declining order of importance):

Vitamin B12 is the precursor of two different cofactor forms that are involved in two very different metabolic reactions (Fig. 22-7). One, catalyzed by methionine synthase (a.k.a. homocysteine methyltransferase), uses methyl-BI2 as a one-carbon donor. The other reaction is catalyzed by methylmalonyl-CoA mutase, which utilizes 5 -deoxyadenosyl-B12 as a cofactor and involves the transfer of a one-carbon unit within the molecule rather than between reactants.

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the isotopic shifts These are needed to limit the number of solutions in a force constant calculation (Sec 42235) To the same end, a number of isotopomers of 0x0-anions were investigated by 1R In order to obtain sharp bands, the following species are sometimes incorporated in high dilution in solid matrices, such as alkali halides: ClO,, SO: , SeO: , CrOi- and WO (Becher et al, 1973 and 1976) Isotopic shifts between "Mo and 'O0Mo were measured in order to obtain a force field of the MOO: anion (Miiller et al, 1974) For more information about the metal isotope effect on molecular vibrations, the review of Mohan et al (1975) is recommended.

In software engineering, two different kinds of requirements have traditionally been identified: functional requirements, which say what the system should do, and non-functional requirements, which say what constraints there are on the system and its development. For example, a functional requirement for a word processor may be that it should support a variety of formatting styles. This requirement might then be decomposed into more specific requirements detailing the kind of formatting required such as formatting by paragraph, by character, and by document, down to a very specific level such as that character formatting must include 20 typefaces, each with bold, italic, and standard options. A non-functional requirement for a word processor might be that it must be able to run on a variety of platforms such as PCs, Macs and Unix machines. Another might be that it must be able to function on a computer with 64 MB RAM. A different kind of non-functional requirement would be that it must be delivered in six months' time. This represents a constraint on the development activity itself rather than on the product being developed. If we consider interaction devices in general, other kinds of non-functional requirements become relevant such as physical size, weight, color, and production

where 129Xe is the excess Xe attributed to the decay of 129I, 127I is the concentration of stable, nonradiogenic 127I, l is the decay constant for 129I, and (129I/127I)0 is the ratio of the abundance of the iodine isotopes at the time of isolation from galactic nucleosynthesis This latter ratio is derived from theories of nucleosynthesis and is 1024 The decay of extinct 244Pu is deduced from excess abundances of the nuclides 136 Xe, 134Xe, and 132Xe, produced by the spontaneous ssion of 244Pu Uncertainties arise because there is no stable isotope of Pu that can be used in the way that 127I is used in Equation (360) and the use of other heavy nuclides 238U or 252Th as substitutes leads to dif culties due to differences in primordial production and chemistry By far the most important dating method involves the decay of 14C (t1/2 5730 y).

Since the vibrations of molecules are anharmonic, it is important to remember that the frequencies of the different isotopomers only afford the same force constant if the amplitudes are assumed to be infinitesimally small The distortion which is caused by the different anharmonicity of the vibrations in isotopomeric molecules is often small compared to the accuracy of the measurement This is especially true for small isotopic shifts (about 1-5 cm I ) As a result of the development of new, improved techniques (eg, FT-spectrometers, matrix isolation), frequencies can sometimes be determined with an accuracy of more than 01 cm I If isotopic shifts can be measured so accurately, they have to be corrected for anharmonicity, even if the isotopic shift is in the range of a few cm-'.

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